Tuning emission wavelength and redox properties through position of the substituent in iridium(III) cyclometallated complexes.
نویسندگان
چکیده
Cyclometallated phenyls with substituents para to the metal have a larger impact on the redox potentials and emission of complexes [Ir(R-ppz)(2)(bipy)][PF(6)] than substituents at the meta position and hence enable tuning of emission wavelength over a wider range using the same substituent.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 40 5 شماره
صفحات -
تاریخ انتشار 2011